
1. Open the photo you want to change.
2. Go to Image>Adjustments>Desaturate or simply press Shift+Ctrl+U.
3. Select the History Brush and adjust its size as needed.
3. Carefully brush the areas you want to stand out from the black and white background. Zoom in and change the brush size when needed.
4. Enjoy your result and prepare for some post-work…
If you want to take things one step further, you can also apply a frame to your photo, a very quick and effective technique for this was described here. Good luck!
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